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Título : Application of TLC and LA ICP SF MS for speciation of S, Ni and V in petroleum samples
Autor : Vorapalawut, Nopparat
Martinez Labrador, Mauro
Pohl, Pawel
Caetano, Manuel
Chirinos, José
Arnaudguilhem, Carine
Bouyssiere, Brice
Shiowatana, Juwadee
Lobinski, Ryszard
Palabras clave : LA ICP SF MS TLC Crude oil Speciation Metals
Fecha de publicación : 2012
Resumen : A coupling of thin layer chromatography with laser ablation ICP SF MS was developed for the fractionation of Ni, V, Fe and S in crude oil and its fractions (saturate, aromatic, resin and asphaltene). The detection limits were 18 ng g 1 and 23 ng g 1 for nickel and vanadium, respectively, and a sample could be characterized in terms of the metal distribution as a function of species polarity within 10 min. The method was used to characterize the metal distribution in crude oils of different origins and their different fractions.
URI : http://hdl.handle.net/10872/8761
ISSN : 0039-9140
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