Repositorio Institucional
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https://saber.ucv.ve/handle/10872/6381
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| Title: | Picosecond measurement of the nonlinear refractive index of new salts of carboxylate anions with chiral ammonium cations |
| Authors: | Rodriguez, Luis Héctor, Gutiérrez Javier, Hernandez Marcano, Aristides Sylla, Mamadou Gifard, M. Soscum, Humberto Nguyen Phu, Xuang Simos |
| Keywords: | Third-order nonlinearly Molecular second-order hyperpolarizability Z-scan technique Nonlinear refraction index |
| Issue Date: | 1-Dec-2004 |
| Publisher: | Optical Materials |
| Citation: | Opt. Mat. vol. 27, issue 3 (2004), 641–646 |
| Abstract: | The third order nonlinear optical properties of novel carboxylate anions with chiral amines and ammonium cations have been studied by a new alternative of the classical z-scan technique with picosecond laser pulses (pulse duration of 30 ps at 1064 nm wavelength). The materials do not present linear and nonlinear (two-photon) absorptions at the wavelength and the intensities used for the experiments. The non-resonant molecular second order hyperpolarizability γ obtained can reach 4.4 × 10−48 SI. These values are two and three orders of magnitude larger than those CS2 and of C6H6 respectively. |
| URI: | http://hdl.handle.net/10872/6381 |
| Appears in Collections: | Artículos Publicados |
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