Repositorio Institucional
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https://saber.ucv.ve/handle/10872/14418
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| Title: | Application of femtosecond laser ablation inductively coupled plasma mass spectrometry for quantitative analysis of thin Cu(In,Ga)Se2 solar cell films |
| Authors: | Lee, Seokhee Gonzalez, Jhanis J. Yoo, Jong H. Chirinos, José Russo, Richard E. Jeong, Sungho |
| Keywords: | Femtosecond LA-ICP-MS CIGS Solar cell Composition |
| Issue Date: | 10-Feb-2017 |
| Abstract: | Thiswork reports that the composition of Cu(In,Ga)Se2 (CIGS) thin solar cell films can be quantitatively predicted with high accuracy and precision by femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs-LA-ICP-MS). It is demonstrated that the results are strongly influenced by sampling conditions during fs-laser beam (λ = 1030 nm, τ = 450 fs) scanning on the CIGS surface. The fs-LA-ICP-MS signals measured at optimal sampling conditions generally provide a straight line calibration with respect to the reference concentrations measured by inductively coupled plasma optical emission spectroscopy (ICP-OES). The concentration ratios predicted by fs-LA-ICP-MS showed high accuracy, to 95–97% of the values measured with ICP-OES, for Cu, In, Ga, and Se elements. |
| URI: | http://hdl.handle.net/10872/14418 |
| ISSN: | 0040-6090 |
| Appears in Collections: | Artículos Publicados |
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