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> Mi ssbauer study of the evolution of a laterite iron mineral based catalyst: Effect of the activation treatment
Please use this identifier to cite or link to this item: https://saber.ucv.ve/handle/10872/11493

Title: Mi ssbauer study of the evolution of a laterite iron mineral based catalyst: Effect of the activation treatment
Authors: Cubeiro, Maria Luisa
Goldwasser, Mireya
Pérez Zurita, M. Josefina
Franco, C.
González-Jiménez, F.
Jaimes, E.
Issue Date: 20-Jul-2015
Abstract: The syngas reaction has been studied using a laterite iron mineral, promoted with K and Mn. In situ activation under syngas, as well as pre-treatment with H2 followed by CO under mild and more severe conditions were tested. These activation procedures led to different iron phase compositions and to different catalytic selectivities. The C2-C4/CH4 ratio was significantly lower for those catalysts which after reaction showed the presence of hexagonal carbide and magnetite compared to the solid, which showed the highest proportion of Hagg carbide.
URI: http://hdl.handle.net/10872/11493
ISSN: 0304-3843
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