SABER UCV >
1) Investigación >
Artículos Publicados >
Por favor, use este identificador para citar o enlazar este ítem:
|Título : ||New Co-Ni catalyst systems used for methane dry reforming based on supported catalysts over an INT-MM1 mesoporous material and a perovskite-like oxide precursor LaCo0.4Ni0.6O3|
|Autor : ||González, Orlando|
|Palabras clave : ||Dry reforming; Methane; Perovskite; Hydrogen; INT-MM1 silica|
|Fecha de publicación : ||2005|
|Editorial : ||Catalysis Today|
|Citación : ||Catalysis Today 107–108 (2005) 436–443|
|Resumen : ||To obtain a new, better-dispersed catalytic material on a stable substrate for the production of H2 and CO by reforming of CH4 with CO2, a
series of supported Ni-Co catalysts (designated C1, C2, C3 and C6) was prepared by impregnation of a mesoporous silica material (INTMM1).
Catalyst reactivity was compared with a LaCo0.4Ni0.6O3 perovskite-like oxide synthesized by the citrate sol–gel method. All materials
were characterized by several physico-chemical techniques: AA, EDX, XDR, IR, BET surface area and TPR. Significant differences in
activity and product distribution were observed among the catalytic systems in the reforming reaction. The supported materials were active for
the reaction, but selectivity for H2 depended on the bimetallic composition of each solid. The different product distributions observed could be
attributed to the properties of the support and their interaction with the metals. Among all of the solids investigated, C3 was the most selective
toward the production of H2, reaching values of 78%, and the perovskite-like oxide precursor was the most active solid, with conversion of
91%. Both catalyst systems have the same Co/Ni metal ratio (ffi0.7) and were very stable for up to 100 h on stream.
# 2005 Elsevier B.V. All rights reserved.|
|URI : ||http://hdl.handle.net/10872/14201|
|Aparece en las colecciones: ||Artículos Publicados|
Los ítems de DSpace están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.